Some Review Topics for Second Exam 1998
[Although there will be no specific questions on topics from the first exam, you will of course be expected to know about such things as molarity, atomic and molecular weights, balancing equations, names of compounds, etc]

Ionic Equations (for reactions in aqueous solution)
Strong and weak acids and bases
Solubility Rules
Metathesis reactions
    precipitation reactions (from solubility rules)
    neutralization reactions (formation of a weak electrolyte or a non-electrolyte)
    oxidation-reduction ("Redox") reactions (from Activity Series)
Driving force of a reaction
Oxidation
Reduction
Oxidizing Agent
Reducing Agent
Principle of Titration (determination of an unknown concentration)

Force and Work
Energy - Potential and kinetic
Energy units - joule and calorie
System and Surroundings
First Law of Thermodynamics (aka Law of Conservation of Energy)
Internal Energy of a System, E
E = q + w
Exothermic (qsystem <0) and Endothermic (qsystem > 0) Processes
E is a State Function, and is an Extensive property of the system
Enthalpy, H
H = qP
H is a State Function, and is an Extensive property of the system
Enthalpies of Reaction
Calorimetry, calorimeter
Heat Capacity (specific heat of a substance, molar heat capacity of a substance, heat capacity of a calorimeter)
"Coffee cup" (constant pressure) calorimetry
Hess's Law (adding and subtracting equations; adding and subtracting DH's)
Standard enthalpy of Formation - definition and use
Standard States
Determination of DH's using Hess's Law
DHreaction = Sum(DHf's of products) - Sum(DHf's of reactants)

Electromagnetic radiation - wavelength, frequency, amplitude
c = nl
Types of em radiation (from gamma rays to radio waves)
Quantum theory
Planck's constant, h
E = hn
Photoelectric effect and its explanation - photons
Atomic line spectra
    hydrogen spectrum - Balmer series
Bohr model for H atom
    quantized electron orbits
    ground and excited states
    quantum numbers, n
    Rydberg constant
    explanation of atomic spectrum of H
Waves as particles, particles as waves (de Broglie)
    l = h/mv
Uncertainty Principle (Heisenberg)
    position-momentum or frequency (energy)-time

Questions on the following topics, which were first presented in the lecture on wednesday, October 21, will count for no more (and maybe less) than 10% of the exam. This material will also be covered in the third exam.

wave mechanics/quantum mechanics
wave functions
orbitals, electron density distributions
other quantum numbers (l, m)
possible values of l and m
"meanings" of n, l, and m
s (l=0 and p (l=1) orbitals (names & shapes)
d (l=2) and f (l=3) orbitals (names only)

The following topics were not covered in wednesday's lecture and will appear in the third exam only.

relative energies of orbitals in many-electron atoms
effective nuclear charge and screening
Electron spin (quantum number s)
Pauli exclusion principle
Electron configurations and the Periodic Table