Ionic Equations (for reactions in aqueous solution)
Strong and weak acids and bases
Solubility Rules
Metathesis reactions
precipitation reactions (from solubility rules)
neutralization reactions (formation of a weak electrolyte
or a non-electrolyte)
oxidation-reduction ("Redox") reactions (from Activity
Series)
Driving force of a reaction
Oxidation
Reduction
Oxidizing Agent
Reducing Agent
Principle of Titration (determination of an unknown concentration)
Force and Work
Energy - Potential and kinetic
Energy units - joule and calorie
System and Surroundings
First Law of Thermodynamics (aka Law of Conservation of Energy)
Internal Energy of a System, E
E = q + w
Exothermic (qsystem <0) and Endothermic (qsystem
> 0) Processes
E is a State Function, and is an Extensive property of the system
Enthalpy, H
H = qP
H is a State Function, and is an Extensive property of the system
Enthalpies of Reaction
Calorimetry, calorimeter
Heat Capacity (specific heat of a substance, molar heat capacity of
a substance, heat capacity of a calorimeter)
"Coffee cup" (constant pressure) calorimetry
Hess's Law (adding and subtracting equations; adding and subtracting
DH's)
Standard enthalpy of Formation - definition and use
Standard States
Determination of DH's using Hess's Law
DHreaction = Sum(DHf's
of products) - Sum(DHf's of reactants)
Electromagnetic radiation - wavelength, frequency, amplitude
c = nl
Types of em radiation (from gamma rays to radio waves)
Quantum theory
Planck's constant, h
E = hn
Photoelectric effect and its explanation - photons
Atomic line spectra
hydrogen spectrum - Balmer series
Bohr model for H atom
quantized electron orbits
ground and excited states
quantum numbers, n
Rydberg constant
explanation of atomic spectrum of H
Waves as particles, particles as waves (de Broglie)
l = h/mv
Uncertainty Principle (Heisenberg)
position-momentum or frequency (energy)-time
Questions on the following topics, which were first presented in the lecture on wednesday, October 21, will count for no more (and maybe less) than 10% of the exam. This material will also be covered in the third exam.
wave mechanics/quantum mechanics
wave functions
orbitals, electron density distributions
other quantum numbers (l, m)
possible values of l and m
"meanings" of n, l, and m
s (l=0 and p (l=1) orbitals (names & shapes)
d (l=2) and f (l=3) orbitals (names only)
The following topics were not covered in wednesday's lecture and will appear in the third exam only.
relative energies of orbitals in many-electron atoms
effective nuclear charge and screening
Electron spin (quantum number s)
Pauli exclusion principle
Electron configurations and the Periodic Table